Low-impact development for impervious surface connectivity mitigation: assessment of directly connected impervious areas (DCIAs)

Urbanization increases directly connected impervious area (DCIA), the impervious area that is hydraulically connected to downstream drainage by closed pipelines. Although the benefits of low-impact development (LID) have been examined in other studies, its effect on alleviating DCIA levels has seldom been assessed. This study measured the DCIA of urban watersheds in Houston, TX, USA. Five land-use types were categorized and the contribution of LID facilities to reducing DCIA in each type was estimated by using Sutherland's equations. The results showed (1) DCIA in commercial areas was greater than that in residential areas, especially for big-box retailers; (2) the percentage of DCIA reduction by LID varied by land-use type; and (3) optimal combinations of LID application could maximize the effectiveness of DCIA reduction. The results contribute to prioritizing land-use type for implementing LID practices and providing local governments with a useful measure to estimate runoff volume.     

Production and characterization of biodiesel from Eriobotrya Japonica seed oil: an optimization study

Biodiesel is now-a-days recognized as a real potential alternative to petroleum-derived diesel fuel due to its number of desirable characteristics. However, its higher production cost resulting mainly due to use of costly food-grade vegetable oils as raw materials is the major barrier to its economic viability. Present work is an attempt to explore the potential of Eriobotrya japonica seed oil for the synthesis of biodiesel using alkali-catalyzed transesterification. Optimization of production parameters, namely molar ratio of alcohol to oil, amount of catalyst, reaction time and temperature, was carried out using Taguchi method. Fatty acid composition of both oil and biodiesel was determined using GC and H¹ NMR. Alcohol to oil molar ratio of 6:1, catalyst amount of 1% wt/wt, 2 h reaction time and 50 ^°C reaction temperature were found to be the optimum conditions for obtaining 94.52% biodiesel. Highest % contribution was shown by the ‘amount of catalyst’ (67.32%) followed by molar ratio of alcohol to oil (25.51%). Major fuel properties of E. japonica methyl esters produced under optimum conditions were found within the specified limits of ASTM D6751 for biodiesel, hence it may be considered a prospective substitute of petro-diesel.     

Health risk assessment of potentially harmful elements and dietary minerals from vegetables irrigated with untreated wastewater,Pakistan

In the developing world, vegetables are commonly grown in suburban areas irrigated with untreated wastewater containing potentially harmful elements (PHEs). In Pakistan, there is no published work on the bioaccessibility aspect of PHEs and dietary minerals (DMs) in sewage-irrigated soil or the vegetables grown on such soils in Pakistan. Several industrial districts of Pakistan were selected for assessment of the risk associated with the ingestion of vegetables grown over sewage-irrigated soils. Both the total and bioaccessible fraction of PHEs (Cd, Co, Cr, Ni, and Pb) and DMs (Fe, Cu, Mn, Zn, Ca, Mg, and I) in soils and vegetable samples were measured. The concentrations of these PHEs and DMs in sewage-irrigated and control soils were below published upper threshold limits. However, compared to control soils, sewage irrigation over the years decreased soil pH (7.7 vs 8.1) and enhanced dissolved organic carbon (1.8 vs 0.8 %), which could enhance the phyto-availability of PHEs and DMs to crops. Of the PHEs and DMs, the highest transfer factor (soil to plant) was noted for Cd and Ca, respectively. Concentrations of PHEs in most of the sewage-irrigated vegetables were below the published upper threshold limits, except for Cd in the fruiting portion of eggplant and bell pepper (0.06–0.08 mg/kg Cd, dry weight) at three locations in Gujarat and Kasur districts. The bioaccessible fraction of PHEs can reduce the context of dietary intake measurements compared to total concentrations, but differences between both measurements were not significant for Cd. Since the soils of the sampled districts are not overly contaminated compared to control sites, vegetables grown over sewage-irrigated soils would provide an opportunity to harvest mineral-rich vegetables potentially providing consumers 62, 60, 12, 104, and 63 % higher dietary intake of Cu, Mn, Zn, Ca, and Mg, respectively. Based on Fe and vanadium correlations in vegetables, it is inferred that a significant proportion of total dietary Fe intake could be contributed by soil particles adhered to the consumable portion of vegetables. Faecal sterol ratios were used to identify and distinguish the source of faecal contamination in soils from Gujranwala, Gujarat, and Lahore districts, confirming the presence of human-derived sewage biomarkers at different stages of environmental alteration. A strong correlation of some metals with soil organic matter concentration was observed, but none with sewage biomarkers.     

Concentration of trace elements in feathers of waterfowl,Korea

Cadmium (Cd), lead (Pb), chromium (Cr), copper (Cu), manganese (Mn), zinc (Zn), and iron (Fe) were analyzed in the breast feather of white-fronted geese (Anser albifrons, n?=?15), mallards (Anas platyrhynchos, n?=?4), and spot-billed ducks (Anas poecilorhyncha, n?=?13) found dead in Gimpo, Korea. All of the mallards and eight of the 13 spot-billed ducks had embedded shot. Concentrations of Pb, Cr, Cu, Mn, Zn, and Fe were significantly different among waterfowl species. Mallards with embedded shot had relatively higher Pb, Cr, Mn, and Fe concentrations than the other species. Cd and Cr in feathers of waterfowl species were within the range reported for other birds, and no specimen exceeded the tentative threshold effect levels of Cd (2 μg/g dry weight (dw)) and Cr (2.8 μg/g dw) for birds. However, Pb in feathers of all four mallards and two spot-billed ducks exceeded the threshold for deleterious effects (>4 μg/g dw). Essential elements such as Cu, Mn, Zn, and Fe in the feather of waterfowl species were not at toxic levels and within the background or normal range for the homeostatic mechanisms.     

Physicochemical parameters aid microbial community? A case study from marine recreational beaches,Southern India

A total of 176 (water and sediment) samples from 22 stations belonging to four different (urban, semi-urban, rural, and holy places) human habitations of Tamil Nadu beaches were collected and analyzed for physiochemical and microbial parameters during 2008–2009. Bacterial counts were two- to tenfold higher in sediments than in water due to strong bacterial aggregations by dynamic flocculation and rich organic content. The elevated bacterial communities during the monsoon explain rainfalls and several other wastes from inlands. Coliform counts drastically increased at holy and urban places due to pilgrimage and other ritual activities. Higher values of the pollution index (PI) ratio (>1) reveals, human fecal pollutions affect the water quality. The averaged PI ratio shows a substantial higher microbial contamination in holy places than in urban areas and the order of decreasing PI ratios observed were: holy places?>?urban areas?>?semi-urban areas?>?rural areas. Correlation and factor analysis proves microbial communities were not related to physicochemical parameters. Principal component analysis indicates 55.32 % of the total variance resulted from human/animal fecal matters and sewage contaminants whereas 19.95 % were related to organic contents and waste materials from the rivers. More than 80 % of the samples showed a higher fecal coliform and Streptococci by crossing the World Health Organization's permissible limits.     

Lead and cadmium contaminations in feathers of heron and egret chicks

In birds, concentrations of heavy metal contaminants were associated with their diet and environmental quality. This study presents concentrations of lead and cadmium in feathers and the relationship between concentrations in the feather and stomach content of three species of heron and egret chicks. Cadmium concentrations were higher in the Little Egret (geomean 0.75 μg/g dry weight) and Black-crowned Night Heron (geomean 0.88 μg/g dry weight) chicks than in Grey Heron chicks (geomean 0.48 μg/g dry weight). Lead and cadmium concentrations had significant correlations between feathers and stomach contents of heron and egret chicks. The mean lead and cadmium concentrations in feathers were within the background levels for wild birds. Heron and egret species forage around breeding colony (4–7 km). Lead and cadmium concentrations in heron and egret chicks were moderately associated with those of prey concentrations. These results suggest that contaminant concentrations such as lead and cadmium in feathers of heron and egret chicks can reflect local heavy metal contaminations and serve as a great biological indicator for monitoring heavy metal contamination. In addition, the feathers can be a routine monitoring tool over time and space without harming the wild birds.     

Inhibition of residual <Emphasis Type="Italic">n</Emphasis>-hexane in anaerobic digestion of lipid-extracted microalgal wastes and microbial community shift

Converting lipid-extracted microalgal wastes to methane (CH₄) via anaerobic digestion (AD) has the potential to make microalgae-based biodiesel platform more sustainable. However, it is apparent that remaining n-hexane (C₆H₁₄) from lipid extraction could inhibit metabolic pathway of methanogens. To test an inhibitory influence of residual n-hexane, this study conducted a series of batch AD by mixing lipid-extracted Chlorella vulgaris with a wide range of n-hexane concentration (～10 g chemical oxygen demand (COD)/L). Experimental results show that the inhibition of n-hexane on CH₄ yield was negligible up to 2 g COD/L and inhibition to methanogenesis became significant when it was higher than 4 g COD/L based on quantitative mass balance. Inhibition threshold was about 4 g COD/L of n-hexane. Analytical result of microbial community profile revealed that dominance of alkane-degrading sulfate-reducing bacteria (SRB) and syntrophic bacteria increased, while that of methanogens sharply dropped as n-hexane concentration increased. These findings offer a useful guideline of threshold n-hexane concentration and microbial community shift for the AD of lipid-extracted microalgal wastes.     

A comparative study on per capita waste generation according to a waste collecting system in Korea

As cities are becoming increasingly aware of problems related to conventional mobile collection systems, automated pipeline-based vacuum collection (AVAC) systems have been introduced in some densely populated urban areas. The reasons are that in addition to cost savings, AVAC systems can be efficient, hygienic, and environmentally friendly. Despite difficulties in making direct comparisons of municipal waste between a conventional mobile collection system and an AVAC system, it is meaningful to measure the quantities in each of these collection methods either in total or on a per capita generation of waste (PCGW, g/(day*capita)) basis. Thus, the aim of this study was to assess the difference in per capita generation of household waste according to the different waste collection methods in Korea. Observations on household waste show that there were considerable differences according to waste collection methods. The value of per capita generation of food waste (PCGF) indicates that a person in a city using AVAC produces 60 % of PCGF (109.58 g/(day*capita)), on average, compared with that of a truck system (173.10 g/(day*capita)) as well as 23 %p less moisture component than that with trucks. The value of per capita generation of general waste (PCGG) in a city with an AVAC system showed 147.73 g/(day*capita), which is 20 % less than that with trucks delivered (185 g/(day*capita)). However, general waste sampled from AVAC showed a 35 %p increased moisture content versus truck delivery.     

Exploring the risks and benefits of flexibility in biodiversity offset location in a case study of migratory shorebirds

Biodiversity offsets aim to counterbalance the residual impacts of development on species and ecosystems. Guidance documents explicitly recommend that biodiversity offset actions be located close to the location of impact because of higher potential for similar ecological conditions, but allowing greater spatial flexibility has been proposed. We examined the circumstances under which offsets distant from the impact location could be more likely to achieve no net loss or provide better ecological outcomes than offsets close to the impact area. We applied a graphical model for migratory shorebirds in the East Asian–Australasian Flyway as a case study to explore the problems that arise when incorporating spatial flexibility into offset planning. Spatially flexible offsets may alleviate impacts more effectively than local offsets; however, the risks involved can be substantial. For our case study, there were inadequate data to make robust conclusions about the effectiveness and equivalence of distant habitat-based offsets for migratory shorebirds. Decisions around offset placement should be driven by the potential to achieve equivalent ecological outcomes; however, when considering more distant offsets, there is a need to evaluate the likely increased risks alongside the potential benefits. Although spatially flexible offsets have the potential to provide more cost-effective biodiversity outcomes and more cobenefits, our case study showed the difficulty of demonstrating these benefits in practice and the potential risks that need to be considered to ensure effective offset placement.